[2,2′-Bis(pyridin-2-ylmethoxy)biphenyl-κ4 N,O,O′,N′]bis(nitrato-κ2 O,O′)cadmium
نویسندگان
چکیده
In the title compound, [Cd(NO(3))(2)(C(24)H(20)N(2)O(2))], the Cd(II) ion is eight-coordinated by one ligand and two nitrate ions. There are C-H⋯O hydrogen bonds and C-H⋯π inter-actions and π-π inter-actions [centroid-centroid distance = 3.319 (1) Å] in the crystal structure.
منابع مشابه
[1,2-Bis(pyridin-2-ylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)cobalt(II)
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))], the Co(II) ion is six-coordinated in a distorted octa-hedral environment defined by two O and two N atoms from the ligand and by two O atoms from two nitrate anions. A two-dimensional network parallel to the ab plane is built up by C-H⋯O hydrogen bonds, which link adjacent mol-ecules in the crystal structure.
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The reaction of cadmium nitrate and sodium nitrite in the presence of 1,10-phenanthroline yields the mixed nitrate-nitrite title complex, [Cd(NO(2))(1.75)(NO(3))(0.25)(C(12)H(8)N(2))(2)]. The metal ion is bis-chelated by two N-heterocycles as well as by the nitrate/nitrite ions in a distorted dodeca-hedral CdN(4)O(4) coordination environment. One nitrite group is ordered; the other is disordere...
متن کاملcatena-Poly[[bis(nitrato-κO)cadmium]bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Cd(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the six-coordinated Cd(II) ion is located on an inversion center and has a distorted octa-hedral environment defined by four N atoms from four 1,4-bis-(pyridin-3-ylmeth-oxy)benzene ligands and two O atoms from two nitrate anions. The ligands link the Cd(II) ions into a ribbon-like structure running along [201]. One O atom of the n...
متن کاملBis{μ-2-[3-carboxylatomethyl-4-(phenylsulfanyl)phenyl]propanoato-κ4 O,O′:O′′,O′′′}bis[(2,2′-bipyridine-κ2 N,N′)cadmium]
In the title complex, [Cd(2)(C(17)H(14)O(4)S)(2)(C(10)H(8)N(2))(2)], which was hydro-thermally synthesized, the Cd(II) cation is hexa-coordinated in a distorted octa-hedral geometry by two N atoms from a 2,2'-bipyridine ligand and by four O atoms from two different 2-[3-carboxyl-atometh-yl-4-(phenyl-sulfan-yl)phen-yl]propano-ate ligands, forming a cyclic dimetallic complex.
متن کاملcatena-Poly[[bis(nitrato-κO)cobalt(II)]-bis[μ-1,4-bis(pyridin-3-ylmethoxy)benzene-κ2 N:N′]]
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))(2)](n), the Co(II) ion is located on an inversion center and is six-coordinated in an octa-hedral environment defined by four N atoms of the pyridine rings and two O atoms of the nitrate anions. The ligands link the Co(II) ions into a linear chain running along [201]. One O atom of the nitrate ligand is disordered over two positions with ...
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